Cleaning up Hybrid Battery Electrodes Improves Capacity and Lifespan
April 22, 2016 | PNNLEstimated reading time: 5 minutes
Hybrid batteries that charge faster than conventional ones could have significantly better electrical capacity and long-term stability when prepared with a gentle-sounding way of making electrodes.
Called ion soft-landing, the high-precision technique resulted in electrodes that could store a third more energy and had twice the lifespan compared to those prepared by a conventional method, the researchers report today in Nature Communications. Straightforward to set up, the method could eventually lead to cheaper, more powerful, longer-lasting rechargeable batteries.
"This is the first time anyone has been able to put together a functioning battery using ion soft-landing," said chemist and Laboratory Fellow Julia Laskin of the Department of Energy's Pacific Northwest National Laboratory.
The advantages come from soft-landing's ability to build an electrode surface very specifically with only the most desirable molecules out of a complex mixture of raw components.
"It will help us unravel important scientific questions about this energy storage technology, a hybrid between common lithium rechargeable batteries and supercapacitors that have very high energy density," said lead author, PNNL chemist Venkateshkumar Prabhakaran.
A different kind of hybrid
Although lithium ion rechargeable batteries are the go-to technology for small electronic devices, they release their energy slowly, which is why hybrid electric vehicles use gasoline for accelerating, and take a long time to recharge, which makes electric vehicles slower to "fill" than their gas-powered cousins.
One possible solution is a hybrid battery that crosses a lithium battery's ability to hold a lot of charge for its size with a fast-charging supercapacitor. PNNL chemists wanted to know if they could make superior hybrid battery materials with a technology — called ion soft-landing — that intricately controls the raw components during preparation.
To find out, Laskin and colleagues created hybrid electrodes by spraying a chemical known as POM, or polyoxometalate, onto supercapacitor electrodes made of microscopically small carbon tubes. Off-the-shelf POM has both positively and negatively charged parts called ions, but only the negative ions are needed in hybrid electrodes.
Limited by its design, the conventional preparation technique sprays both the positive and negative ions onto the carbon nanotubes. Ion soft-landing, however, separates the charged parts and only sets down the negative ions on the electrode surface. The question that Laskin and team had was, do positive ions interfere with the performance of hybrid electrodes?
To find out, the team made centimeter-sized square hybrid batteries out of POM-carbon nanotube electrodes that sandwiched a specially developed ionic liquid membrane between them.
"We had to design a membrane that separated the electrodes and also served as the battery's electrolyte, which allows conduction of ions," said Prabhakaran. "Most people know electrolytes as the liquid sloshing around within a car battery. Ours was a solid gel."
They tested this mini-hybrid battery for how much energy it could hold and how many cycles of charging and discharging it could handle before petering out.
They compared soft-landing with conventionally made hybrid batteries, which were made with a technique called electrospray deposition. They used an off-the-shelf POM containing positively charged sodium ions.
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